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Image Search Results
Journal: Langmuir : the ACS journal of surfaces and colloids
Article Title: Axial Confocal Tomography of Capillary-Contained Colloidal Structures.
doi: 10.1021/acs.langmuir.7b03039
Figure Lengend Snippet: Figure 2: Vertical ACT yz−slices taken through the colloidal fluids allow the rotational isotropy of these systems to be confirmed, providing a benchmark for the classical 3D confocal reconstruction algorithms. (a) PMMA particles density- and index-matched in a TCE:DHN mixture. Note, this yz−slice through the fluid appears isotropic, akin to the xy−slice shown in Fig. 1(d). (b) To optimize the quality of the ACT images, an accurate matching of the refractive indices of all optical elements downstream of the objective is necessary, as achieved here for the PTFEMA:PtBMA suspension. In particular, the slight aberration- induced smearing of PMMA colloids in (a), is completely eliminated here. Changing from fused silica (b) to borosilicate (c) capillary does not strongly deteriorate the optical quality, as long as the immersion fluid is index-matched with the capillary wall. (d) For fully index- matched suspensions of PTFEMA:PtBMA, even the high-density solid colloidal sediments, prepared by settling in a centrifuge, appear perfectly isotropic, further emphasizing the ACT capabilities.
Article Snippet: These confocal cross sections were obtained through the narrow (yz-) wall of the rectangular 0.1×2×50 mm
Techniques: Suspension
Journal: Langmuir : the ACS journal of surfaces and colloids
Article Title: Axial Confocal Tomography of Capillary-Contained Colloidal Structures.
doi: 10.1021/acs.langmuir.7b03039
Figure Lengend Snippet: Figure 3: Artificial particle chains in ’side-view’ ACT images of colloidal suspensions. These confocal cross sections were obtained through the narrow (yz-) wall of the rectan- gular 0.1 ×2 ×50 mm borosilicate VitrocomTM capillaries, with the Nikon type A oil used for objective immersion. (a) A dense fluid of PMMA colloids in a density- and index- matching TCE:DHN solvent exhibits z−aligned artificial chains (see also Supplementary Video 3). (b) The chains appear in solid sediments of the same particles, as well. Compare to Fig. 2(d), where a similar sediment is shown to be completely isotropic. (c) Larger intra-chain particle separations occur in dilute suspensions, as if the particles repel by electrostatics. (d) These artificial chains, born by light refraction at the walls of the capillary, are visible even for the polar suspensions, where ǫ ≈82 and significant ion concentrations are present. With the intra-chain particle separations far exceeding the Debye length, chain formation cannot be attributed to the electrostatic interactions.
Article Snippet: These confocal cross sections were obtained through the narrow (yz-) wall of the rectangular 0.1×2×50 mm
Techniques: Solvent